Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 4 (April 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m231    [ doi:10.1107/S1600536813006831 ]

catena-Poly[[copper(I)-[mu]-2,6-bis­[4-(pyridin-2-yl)thia­zol-2-yl]pyridine] hexa­fluoridophosphate acetonitrile monosolvate] from single-crystal synchrotron data

L. Xiao, M. Bhadbhade and A. T. Baker

Abstract: The title complex, {[Cu(C21H13N5S2)]PF6·CH3CN}n, was formed immediately on adding together a methanol solution containing copper(I) ions and a methanol solution of 2,6-bis­[4-(pyridin-2-yl)thia­zol-2-yl]pyridine. Crystallographic studies of the complex reveal a coordination polymer with the ligand acting as a bis­(bidentate) ligand with the pyridine N atom not coordinating a metal centre. The CuI atom is four-coordinate with approximately tetra­hedral stereochemistry: the N4 donor set is provided by bipyridine-like moieties of the two heterocyclic ligands. Parallel chains of the coordination polymer run along the b-axis direction with the disordered (0.50:0.50 occupancy ratio) PF6- anions and acetonitrile solvent mol­ecules located between the chains.

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