Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 4 (April 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m187-m188    [ doi:10.1107/S1600536813005096 ]

2-Meth­oxy­anilinium trichlorido­stannate(II)

S. Karoui, S. Kamoun and F. Michaud

Abstract: The title compound, (C7H10NO)[SnCl3], is a new compound with non-linear optical (NLO) properties. The structure is pseudocentrosymmetric; the absence of an inversion centre was proved by the Kurtz and Perry method showing a significant second harmonic generation (SHG) signal about ten times lower than that from potassium dihydrogenphosphate. The crystal structure exhibits alternating organic and inorganic layers parallel to the ab plane, which are stabilized by inter­molecular N-H...Cl inter­actions.

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[ doi:10.1107/S1600536813005096/vn2066Isup3.cdx ]
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