Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 4 (April 2013)


metal-organic compounds



wm2711 scheme

Acta Cryst. (2013). E69, m182-m183    [ doi:10.1107/S1600536813003255 ]

[(2R,3S)-Butane-1,2,3,4-tetraol-[kappa]3O1,O2,O3](ethanol-[kappa]O)tris(nitrato-[kappa]2O,O')samarium(III)

J.-H. Xue, X.-H. Hua, L.-M. Yang, Y.-Z. Xu and J.-G. Wu

Abstract: The title SmIII-erythritol complex, [Sm(NO3)3(C2H6O)(C4H10O4)], is isotypic with its Nd, Eu, Y, Gd, Tb and Ho analogues. The SmIII cation exhibits a coordination number of ten and is chelated by a tridentate erythritol ligand and three bidentate nitrate anions. It is additionally coordinated by an O atom of an ethanol molecule, completing an irregular coordination sphere. The Sm-O bond lengths range from 2.416 (2) to 2.611 (2) Å. In the crystal, extensive O-H...O hydrogen bonding involving all hydroxy groups and some of the nitrate O atoms links the molecules into a three-dimensional network.


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[ doi:10.1107/S1600536813003255/wm2711Isup3.cdx ]
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