Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 4 (April 2013)


metal-organic compounds



wm2729 scheme

Acta Cryst. (2013). E69, m190    [ doi:10.1107/S160053681300603X ]

4-(Dimethylamino)pyridinium tetrachloridoferrate(III)

A. Khadri, R. Bouchene, S. Bouacida, H. Merazig and T. Roisnel

Abstract: The title salt, (C7H11N2)[FeCl4], consists of one essentially planar (the r.m.s. deviation for all non-H atoms being 0.004 Å) 4-(dimethylamino)pyridinium cation and a tetrahedral tetrachloridoferrate(III) anion. The cations and anions are arranged in layers parallel to (010). Besides electrostatic interactions, the crystal packing features N-H...Cl and C-H...Cl hydrogen bonds between cations and anions, forming a three-dimensional network.


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