Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 4 (April 2013)


metal-organic compounds



zs2249 scheme

Acta Cryst. (2013). E69, m226    [ doi:10.1107/S160053681300737X ]

cis,cis,cis-(Acetato-[kappa]2O,O')bis[1,2-bis(diphenylphosphanyl)ethane-[kappa]2P,P']ruthenium(II) 0.75-trifluoromethanesulfonate 0.25-chloride

J. Figueira, J. Rodrigues and A. Valkonen

Abstract: In the title RuII carboxylate compound, [Ru(C2H3O2)(C26H24P2)2](CF3O3S)0.75Cl0.25, the distorted tris-bidentate octahedral stereochemistry about the RuII atom in the complex cation comprises four P-atom donors from two 1,2-bis(diphenylphosphanyl)ethane ligands [Ru-P = 2.2881 (13)-2.3791 (13) Å] and two O-atom donors from the acetate ligand [Ru-O = 2.191 (3) and 2.202 (3) Å]. The disordered counter-anions are located on the same site in the structure in a 3:1 ratio, the expanded formula comprising four complex cations, three trifluoromethanesulfonate anions and one chloride anion, with two such formula units in the unit cell.


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