Received 2 April 2013
aBaku State University, Z. Khalilov St 23, Baku, AZ-1148, Azerbaijan,bR.E. Alekseev Nizhny Novgorod State Technical University, 24 Minin St, Nizhny Novgorod, 603950, Russian Federation, and cX-Ray Structural Centre, A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov St, B-334, Moscow 119991, Russian Federation
Correspondence e-mail: email@example.com
The title compound, C16H12NOSSe+·HSO4-, was obtained from a mixture of 3-(4-methoxyphenyl)[1,3]selenazolo[2,3-b][1,3]benzothiazol-4-ium chloride and potassium hydrogen sulfate. In the cation, the benzene ring is twisted by 71.62 (7)° from the tricycle mean plane. In the crystal, O-HO hydrogen bonds link the anions into chains along . The anions in adjacent chains are linked via weak C-HO hydrogen bonds. The crystal packing exhibits short intermolecular contacts between the chalcogen unit and the O atoms: SeO(anion) 2.713 (3), SeO(cation) 2.987 (3) and SO(anion) 2.958 (3) Å.
For details of the synthesis and the biological properties of selenium- and nitrogen-containing heterocycles, see: Back (2009); Mlochowski & Giurg (2009); Mukherjee et al. (2010); Selvakumar et al. (2010). For the synthesis of the starting compound, 3-(4-methoxyphenyl)[1,3]selenazolo[2,3-b][1,3]benzothiazol-4-ium chloride, see: Borisov et al. (2012).
Data collection: SMART (Bruker, 1998); cell refinement: SAINT (Bruker, 1998); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: CV5401 ).
We thank Professor Abel M. Maharramov for fruitful discussions and help in this work.
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