Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 5 (May 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m283    [ doi:10.1107/S1600536813010441 ]


Q. Dang and H. Caiyun

Abstract: In the title compound, [Cd(C8H4N8)(H2O)4]n, 5,5'-(1,4-phenyl­ene)di(tetra­zol-2-ide) (L) ligands bridge CdII atoms into polymeric chains along [201]. The CdII atom is situated on an inversion centre and is coordinated by two N atoms from two L ligands and by four water O atoms in a distorted octa­hedral geometry. In the L ligand, the benzene ring resides on an inversion centre and the tetra­zole rings are twisted from its plane by 22.3 (1)°. An extensive hydrogen-bonding network formed by classical O-H...N and O-H...O inter­actions consolidates the crystal packing, linking the poymeric chains into a three-dimensional structure.

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