Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 5 (May 2013)

inorganic compounds

Acta Cryst. (2013). E69, i32    [ doi:10.1107/S1600536813011033 ]


V. Suchá, J. Kuchár and K. Harms

Abstract: The title compound, [Cu(NH3)4-([mu]2-NC)-Pd(CN)3], is a binuclear copper(II)palladium(II) complex, in which the CuII coordination is defined by four ammine ligands and one bridging cyanide ligand. The Cu-N bond lengths in the base of the resulting CuN5 pyramid are in the range 2.016 (3)-2.024 (3) Å and the apical Cu-N([triple bond]C) distance is 2.385 (4) Å. Based on the [tau] parameter, the shape of the coordination polyhedron is tetra­gonal-pyramidal ([tau] = 0). All atoms of the square-planar tetracyanidopalladate(II) moiety and the CuII ion are located on a mirror plane. The electroneutral mol­ecules inter­act by N-H...N hydrogen bonds, resulting in the formation of a three-dimensional network.

htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file (61.1 kbytes)
[ doi:10.1107/S1600536813011033/ff2104sup0.html ]
Supplementary materials


To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format