Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 5 (May 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m240    [ doi:10.1107/S160053681300785X ]

Bis[2-(hy­droxy­imino)­cyclo­hexan-1-one oximato-[kappa]2N,N']copper(II)

E. Melnic, E. B. Coropceanu and L. Croitor

Abstract: In the title compound, [Cu(C6H9N2O2)2], the CuII atom is located on an inversion center and has a square-planar environment. Two 2-(hy­droxy­imino)­cyclo­hexan-1-one oxim­ate monoanions chelate to the CuII atom and the Cu-N distances are 1.920 (3) and 1.930 (3) Å. There are two short intra­molecular O-H...O hydrogen bonds between the ligands. The complex mol­ecules stack into columns extended along the c axis, with a Cu...Cu distance between adjacent mol­ecules of 3.3060 (3) Å.

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