Received 29 March 2013
aDepartment of Physics, Shri Angalamman College of Engineering and Technology, Siruganoor, Tiruchirappalli 621 105, India,bAnnamalai University, Annamalainagar, Chidambaram, India,cDepartment of Chemistry, Urumu Dhanalakshmi College, Tiruchirappalli, Tamilnadu, India, and dDepartment of Physics, Urumu Dhanalakshmi College, Tiruchirappalli, Tamilnadu, India
Correspondence e-mail: email@example.com
In the title compound, C29H19F3N2, the tetracyclic ring system is essentially planar [maximum deviation from the best plane = 0.076 (1) Å] and makes dihedral angles of 78.10 (5) and 33.71 (4)° with the methylphenyl and fluorophenyl rings, respectively. An intramolecular C-H interaction occurs. In the crystal, pairs of C-H interactions link inversion-related molecules.
For background to organic electroluminescent materials and devices, see: Adachi et al. (1995); Loy et al. (2002) and for the photophysical, electrochemical and mobility properties of phenanthroimidazole derivatives, see: Yuan et al. (2011). For applications of imidazole and phenanthrolene derivatives, see: Moylan et al. (1993); Bu et al. (1996); Wang et al. (2002).
Data collection: APEX2 (Bruker, 2008); cell refinement: APEX2 and SAINT (Bruker, 2008); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: PLATON (Spek, 2009); software used to prepare material for publication: PLATON.
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: GO2084 ).
PS and AP thank Dr Babu Varghese, Senior Scientific Officer, SAIF, IIT, Chennai, India, for the data collection.
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