Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 5 (May 2013)


metal-organic compounds



hb7066 scheme

Acta Cryst. (2013). E69, m265-m266    [ doi:10.1107/S160053681300946X ]

catena-Poly[silver(I)-bis[[mu]-4-methyl-1H-1,2,4-triazole-3(4H)-thione-[kappa]2S:S]-silver(I)-di-[mu]-thiocyanato-[kappa]2S:N;[kappa]2N:S]

K. Kodcharat, C. Pakawatchai and S. Saithong

Abstract: In the title one-dimensional coordination polymer, [Ag2(NCS)2(C3H5N3S)2]n, the AgI atom adopts a distorted tetrahedral AgNS3 geometry. Adjacent AgI atoms in the [001] chain are alternately linked by pairs of bridging 4-methyl-1H-1,2,4-triazole-3(4H)-thione (Hmptrz) ligands (via their S atoms) and double thiocyanate bridges linking through both S and N atoms ([mu]-1,3-SCN). An intrachain N-H...N hydrogen bond occurs between the NH group of the triazole ring and the N atom of the thiocyanate bridging ligand. A (101) sheet structure arises from interchain S...N short contacts [3.239 (3) Å] involving the thiocyanate S atom and the triazole-ring N atom and possible very weak [pi]-[pi] stacking [centroid-centroid separation = 4.0762 (18) Å] between the triazole rings.


htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file
[ doi:10.1107/S160053681300946X/hb7066sup0.html ]
Supplementary materials


moldisplay filedownload file

MDL mol file (3.7 kbytes)
[ doi:10.1107/S160053681300946X/hb7066Isup3.mol ]
Supplementary material


moldisplay filedownload file

MDL mol file (3.7 kbytes)
[ doi:10.1107/S160053681300946X/hb7066Isup4.mol ]
Supplementary material


Notes:

To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster