Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 5 (May 2013)

inorganic compounds

Acta Cryst. (2013). E69, i24    [ doi:10.1107/S1600536813007988 ]


L. Geng

Abstract: The title quaternary compound, dibarium tetra­anti­mony germanium deca­sulfide, Ba2Sb4GeS10, crystallizes in a novel three-dimensional [infinity]3[Sb4GeS10]4- network structure, which is composed of triangular pyramidal SbS3 (site symmetry m..), distorted SbS5 (m..) polyhedra and regular GeS4 (-4..) tetra­hedra. The SbS3 and SbS5 units are connected with each other through corner- and edge-sharing, forming a Sb4S10 layer in the ab plane. The GeS4 tetra­hedra further bridge two neighbouring Sb4S10 layers, forming a three-dimensional [infinity]3[Sb4GeS10]4- network. The Ba2+ cation (..2) is located between two Sb4S10 layers and is coordinated by ten S atoms with Ba-S bond lengths in the range 3.2505 (9)-3.4121 (2) Å.

htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file
[ doi:10.1107/S1600536813007988/jj2163sup0.html ]
Supplementary materials


To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster