Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 5 (May 2013)


metal-organic compounds



lh5600 scheme

Acta Cryst. (2013). E69, m244-m245    [ doi:10.1107/S1600536813008556 ]

(anti-Chloridothiosemicabazide-[kappa]S)bis(triphenylphosphane-[kappa]P)copper(I) 0.48-hydrate

R. Nimthong, C. Pakawatchai, N. Phongphayak and Y. Wattanakanjana

Abstract: In the mononuclear title complex, [CuCl(CH5N3S)(C18H15P)2]·0.48H2O, the CuI ion is in a slightly distorted tetrahedral coordination geometry formed by two P atoms from two triphenylphosphane ligands, one S atom from a thiosemicarbazide ligand and one chloride anion. An intramolecular N-H...N hydrogen bond [graph-set motif S(5)] stabilizes the thiosemicarbazide ligand in its anti conformation, and an intramolecular N-H...Cl hydrogen bond between the hydrazine N-H group and the chloride anion influences the arrangement and orientation of the ligands around the metal center. A weak intramolecular C-H...Cl hydrogen bond is also present. In the crystal, complex molecules are connected through N-H...Cl hydrogen bonds originating from the amide -NH2 group, and through O-H...S and O-H...Cl hydrogen bonds involving the solvent water molecule. Both the direct N-H...Cl hydrogen bonds as well as the bridging hydrogen bonds mediated by the water molecule connect the complex molecules into zigzag chains that propagate along [010]. The solvent water molecule is partially occupied, with a refined occupancy of 0.479 (7).


htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file
[ doi:10.1107/S1600536813008556/lh5600sup0.html ]
Supplementary materials


Notes:

To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster