Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 5 (May 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m259-m260    [ doi:10.1107/S160053681300860X ]

Aqua­bis­(4-methyl­benzene­sulfonato-[kappa]O)([eta]5-penta­methyl­cyclo­penta­dien­yl)rhodium(III) monohydrate

C. P. Roy, P. M. Boyer and J. S. Merola

Abstract: The title half-sandwich rhodium(III) complex, [Rh(C10H15)(C7H7O3S)2(H2O)]·H2O, consists of a [pi]-bonded penta­methyl­cyclo­penta­dienyl group, two [sigma]-bonded tosyl­ate groups and an aqua ligand. The structure displays both inter- and intra­molecular O-H...O hydrogen bonding. The inter­molecular hydrogen bonding results in an extended helical chain along a 21 screw axis parallel to c, due to hydrogen bonding from the coordinating water ligand to the lattice water mol­ecule and then to a sulfonate O atom of a different asymmetric unit.

htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file
[ doi:10.1107/S160053681300860X/pk2474sup0.html ]
Supplementary materials

cdxdisplay filedownload file

Chemdraw file
[ doi:10.1107/S160053681300860X/pk2474Isup3.cdx ]
Supplementary material


To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster