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Acta Cryst. (2013). E69, o816
[ doi:10.1107/S1600536813011276 ]

3-(4-Chlorophenyl)-1-cyclopropyl-2-(2-fluorophenyl)-5-phenylpentane-1,5-dione

T. Srinivasan, G. Senthilkumar, H. Manikandan, M. Gopalakrishnan and D. Velmurugan

Abstract: In the title compound, C26H22ClFO2, the cyclopropane ring is disordered over two orientations, with site-occupancy factors of 0.64 (2) and 0.36 (2). The major occupancy component of the cyclopropane ring makes dihedral angles of 47.6 (7), 50.4 (7) and 65.4 (7)° with the fluoro-, chloro- and unsubstituted benzene rings, respectively [the corresponding values for the minor occupancy component are 47.6 (12), 51.0 (12) and 60.9 (12)°]. An intramolecular C-H...O hydrogen bond occurs. The F and Cl atoms deviate by 0.0508 (12) and 0.0592 (7) Å from the planes of their attached benzene rings. In the crystal, C-H...F hydrogen bonds link the molecules into chains along the b-axis direction.


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