Acta Cryst. (2013). E69, o644 [ doi:10.1107/S1600536813008398 ]
Abstract: In the title compound, C10H11N3O2S, the 1,3-benzodioxole and hydrazinecarbothioamide fragments are nearly planar [(mean deviations from planarity for non-H atoms of 0.0325 (12) Å and 0.0707 (10) Å, respectively] and subtend a dihedral angle of 29.06 (5)°. In the crystal, molecules are linked by pairs of almost linear N-HS hydrogen bonds, forming inversion dimers. These dimers are additionally connected by weaker and strongly bent N-HS interactions into chains along . There is one additional weak N-HO contact which, if considered as an interaction, leads to the formation of a three-dimensional network.
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