Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 5 (May 2013)


organic compounds



rz5052 scheme

Acta Cryst. (2013). E69, o637    [ doi:10.1107/S1600536813008295 ]

[2,7-Diethoxy-8-(4-fluorobenzoyl)naphthalen-1-yl](4-fluorophenyl)methanone

S. Mouri, D. Hijikata, K. Isozaki, N. Yonezawa and A. Okamoto

Abstract: In the molecule of the title compound, C28H22F2O4, the benzoyl groups are aligned almost antiparallel and the fluorobenzene rings form a dihedral angle of 14.12 (7)°. The dihedral angles between the 2,7-diethoxynaphthalene ring system and the benzene rings are 70.00 (4) and 67.28 (4)°. In the crystal, molecules are linked by C-H...O and C-H...F hydrogen bonds, forming layers parallel to the ab plane. The layers are further connected by [pi]-[pi] interactions [centroid-centroid distances of 3.6115 (10) Å] into a three-dimensional structure.


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