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Acta Cryst. (2013). E69, m292-m293
[ doi:10.1107/S1600536813010738 ]

catena-Poly[[bis(2-methoxyaniline-[kappa]N)cadmium]-di-[mu]-thiocyanato-[kappa]2N:S;[kappa]2S:N]

R. Chemli, S. Kamoun and T. Roisnel

Abstract: The structure of the title compound, [Cd(NCS)2(C7H9NO)2]n, consists of cadmium-thiocyanate layers parallel to the ab plane. Pairs of CdII ions are bridged by two end-to-end inversely bridging [mu]-NCS-N:S thiocyanate groups, forming a two-dimensional network with the remaining two trans positions of the octahedrally coordinated CdII ions occupied by the N atoms of two neutral 2-methoxyaniline ligands. The crystal structure is stabilized by intralayer N-H...S hydrogen bonds.


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