Acta Cryst. (2013). E69, m292-m293 [ doi:10.1107/S1600536813010738 ]
Abstract: The structure of the title compound, [Cd(NCS)2(C7H9NO)2]n, consists of cadmium-thiocyanate layers parallel to the ab plane. Pairs of CdII ions are bridged by two end-to-end inversely bridging -NCS-N:S thiocyanate groups, forming a two-dimensional network with the remaining two trans positions of the octahedrally coordinated CdII ions occupied by the N atoms of two neutral 2-methoxyaniline ligands. The crystal structure is stabilized by intralayer N-HS hydrogen bonds.
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