Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 5 (May 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m277    [ doi:10.1107/S1600536813010350 ]


M. Benslimane, Y. K. Redjel, H. Merazig and J.-C. Daran

Abstract: The title mononuclear CuII complex, [Cu(C9H7O2)2(C12H8N2)], is comprised of a CuII cation, two cinnamate (L-) ligands and a 1,10-phenanthroline (phen) ligand. The CuII atom and phen ligand lie on a twofold rotation axis. The CuII atom is coordinated by two O atoms from two carboxyl­ate groups of two (L-) ligands and two N atoms from one phen ligand, exhibiting a distorted square-planar geometry. In the crystal, mol­ecules are assembled into supra­molecular chains parallel to the c axis through weak C-H...O hydrogen bonds involving the phen and cinnamate ligands.

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