Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 5 (May 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m273-m274    [ doi:10.1107/S1600536813010246 ]

Poly[[di­aqua­([mu]4-benzene-1,2,4,5-tetra­carboxyl­ato)tetrakis­(1H-imidazole-[kappa]N3)dicopper(II)] N,N-di­methyl­formamide monosolvate]

X.-F. Zhou, H.-P. Xiao, Y.-J. Zhao and X.-H. Li

Abstract: The asymmetric unit of the polymeric title compound, {[Cu2(C10H2O8)(C3H4N2)4(H2O)2]·C3H7NO}n, contains two independent CuII ions, each coordinated by one water mol­ecule, two imidazole N atoms and two carboxyl­ate O atoms from benzene-1,2,4,5-tetra­carboxyl­ate anions in a distorted square-pyramidal geometry. The benzene-1,2,4,5-tetra­carboxyl­ate anion bridges four CuII ions, forming a polymeric sheet parallel to (010). In the crystal, extensive N-H...O and O-H...O hydrogen bonds link the polymeric sheets and di­methyl­formamide solvent mol­ecules into a three-dimensional supra­molecular structure.

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