Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 6 (June 2013)


metal-organic compounds



bt6910 scheme

Acta Cryst. (2013). E69, m346    [ doi:10.1107/S1600536813014244 ]

{N,N-Bis[bis(2,2,2-trifluoroethoxy)phosphanyl]methylamine-[kappa]2P,P'}bis([eta]5-cyclopentadienyl)titanium(II)

M. Haehnel, S. Hansen, A. Spannenberg and T. Beweries

Abstract: The title compound, [Ti(C5H5)2(C9H11F12NO4P2)], is a four-membered titanacycle obtained from the reaction of Cp2Ti([eta]2-Me3SiC2SiMe3) and CH3N[P(OCH2CF3)2]2 {N,N-bis[bis(trifluoroethoxy)phosphanyl]methylamine, tfepma}. The TiII atom is coordinated by two cyclopentadienyl (Cp) ligands and the chelating tfepma ligand in a strongly distorted tetrahedral geometry. The molecule is located on a mirror plane.


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