Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 6 (June 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m343    [ doi:10.1107/S1600536813014311 ]

Aqua­carbon­yl(ferrocenyldi­thio­phos­phon­ato-[kappa]2S,S')bis­(tri­phenyl­phosphane-[kappa]P)ruthenium(II) dichloromethane mono­solvate

H. Zhu, Q. Ma, H.-T. Shi, Q. Chen and Q.-F. Zhang

Abstract: The structure of the title complex, [FeRu(C5H5)(C5H4OPS2)(CO)(C18H15P)2(H2O)]·CH2Cl2, consists of one neutral [{FcP(O)S2}Ru(CO)(H2O)(PPh3)2] complex [Fc = Fe([eta]5-C5H4)([eta]5-C5H5)] and one CH2Cl2 solvent mol­ecule. The geometry around the RuII atom is pseudo-octa­hedral, with two cis-binding PPh3 ligands and one chelating bidentate [Fc(O)PS2]2- ligand via two S atoms. The average Ru-S and Ru-P bond lengths are 2.434 (1) and 2.398 (1) Å, and the Ru-O and Ru-C bond lengths are 2.157 (3) and 1.826 (4) Å, respectively. In the crystal, pairs of O-H...O hydrogen bonds link adjacent mol­ecules into dimers.

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