Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 6 (June 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m344    [ doi:10.1107/S1600536813014323 ]

Tetra­ethyl­ammonium trichlorido(N,N'-di­methyl­formamide-[kappa]O)zinc

G.-P. Chao, H.-T. Shi, Q. Chen and Q.-F. Zhang

Abstract: The title complex salt, (C8H20N)[ZnCl3(C3H7NO)], contains one [Et4N]+ cation (Et is ethyl) and one [ZnCl3(DMF)]- anion (DMF is di­methyl­formamide). In the anion, the zinc atom is tetra­hedrally coordinated by a DMF ligand via the O atom and by three terminal Cl atoms. The average Zn-Cl bond length and Cl-Zn-Cl angle are 2.243 (11) Å and 114 (3)°, respectively.

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