Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 6 (June 2013)


metal-organic compounds



hb7077 scheme

Acta Cryst. (2013). E69, m316    [ doi:10.1107/S1600536813012300 ]

(O-Methyl dithiocarbonato-[kappa]S)triphenyltin(IV)

F. Javed, S. Ali, W. Shah, M. N. Tahir and H. Ullah

Abstract: In the title compound, [Sn(C6H5)3(C2H3OS2)], the SnIV atom adopts a distorted SnC3S tetrahedral coordination geometry. A short Sn...O contact [2.988 (4) Å] is also present. The phenyl rings are each disordered over two sets of sites with an occupancy ratio of 0.550 (8):0.450 (8). The crystal studied was found to be a racemic twin with a twin component ratio of 0.57 (18):0.43 (18).


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