Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 6 (June 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m340    [ doi:10.1107/S1600536813014128 ]

Tris(aceto­nitrile-[kappa]N)dichlorido(tri­phenyl­phosphane-[kappa]P)ruthenium(II) aceto­nitrile monosolvate

X.-F. Yin, Y. Qin, H.-T. Shi, Q. Chen and Q.-F. Zhang

Abstract: In the title complex, [RuCl2(CH3CN)3(C18H15P)]·CH3CN, the coordination geometry of the RuII atom is distorted octa­hedral, defined by one P atom from a tri­phenyl­phosphane ligand, three N atoms from three aceto­nitrile ligands and two Cl atoms. The three acetronitile ligands linearly bind to the RuII atom, with Ru-N-C angles of 172.6 (2), 179.9 (2) and 171.4 (2)°.

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