[Journal logo]

Volume 69 
Part 6 
Page m341  
June 2013  

Received 6 May 2013
Accepted 21 May 2013
Online 25 May 2013

Key indicators
Single-crystal X-ray study
T = 296 K
Mean [sigma](C-C) = 0.006 Å
R = 0.032
wR = 0.083
Data-to-parameter ratio = 23.4
Details
Open access

Tris(diisopropyl dithiophosphato-[kappa]2S,S')ruthenium(III)

aDepartment of Applied Chemistry, School of Petrochemical Engineering, Changzhou University, Jiangsu 213164, People's Republic of China, and bInstitute of Molecular Engineering and Applied Chemsitry, Anhui University of Technology, Ma'anshan, Anhui 243002, People's Republic of China
Correspondence e-mail: zhangqf@ahut.edu.cn

In the title complex, [Ru(C6H14O2PS2)3], the coordination environment of the RuIII atom is distorted octahedral, defined by six S atoms from three S,S'-bidentate diisopropyl dithiophosphate ligands. The average Ru-S bond length is 2.41 (1) Å and the average S-Ru-S bite angle is 81.13 (19)°.

Related literature

For background to ruthenium complexes, see: Castillo-Villalón et al. (2008[Castillo-Villalón, P., Ramírez, J. & Maugé, F. (2008). J. Catal. 260, 65-74.]); Chianelli et al. (2009[Chianelli, R. R., Berhault, G. & Torres, B. (2009). Catal. Today, 147, 275-286.]); David et al. (2005[David, D., Silvia, E. & Castillo, B. (2005). J. Phys. Chem. B, 109, 22715-22724.]); Leung et al. (2000[Leung, W. H., Lau, K. K., Zhang, Q. F., Wong, W. T. & Tang, B. (2000). Organometallics, 19, 2084-2089.]); Wu et al. (2009[Wu, F. H., Duan, T., Lu, L., Zhang, Q. F. & Leung, W. H. (2009). J. Organomet. Chem. 694, 3844-3851.]). For related structures, see: Jain et al. (2000[Jain, P. U., Munshi, P., Walawalkar, M. G., Rath, S. P., Rajak, K. K. & Lahiri, G. K. (2000). Polyhedron, 19, 801-808.]); Liu et al. (2005[Liu, X., Zhang, Q. F. & Leung, W. H. (2005). J. Coord. Chem. 58, 1299-1305.]).

[Scheme 1]

Experimental

Crystal data
  • [Ru(C6H14O2PS2)3]

  • Mr = 740.92

  • Triclinic, [P \overline 1]

  • a = 8.9676 (8) Å

  • b = 10.5073 (9) Å

  • c = 19.1085 (17) Å

  • [alpha] = 81.281 (2)°

  • [beta] = 88.678 (2)°

  • [gamma] = 82.175 (2)°

  • V = 1763.1 (3) Å3

  • Z = 2

  • Mo K[alpha] radiation

  • [mu] = 0.96 mm-1

  • T = 296 K

  • 0.14 × 0.11 × 0.10 mm

Data collection
  • Bruker APEXII CCD diffractometer

  • Absorption correction: multi-scan (SADABS; Sheldrick, 1996[Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany.]) Tmin = 0.877, Tmax = 0.910

  • 11411 measured reflections

  • 7478 independent reflections

  • 6083 reflections with I > 2[sigma](I)

  • Rint = 0.022

Refinement
  • R[F2 > 2[sigma](F2)] = 0.032

  • wR(F2) = 0.083

  • S = 1.02

  • 7478 reflections

  • 319 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.47 e Å-3

  • [Delta][rho]min = -0.32 e Å-3

Table 1
Selected bond lengths (Å)

Ru1-S1 2.4189 (7)
Ru1-S2 2.4037 (7)
Ru1-S3 2.3981 (7)
Ru1-S4 2.3988 (7)
Ru1-S5 2.4155 (7)
Ru1-S6 2.4199 (7)

Data collection: APEX2 (Bruker, 2007[Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2007[Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: HY2626 ).


Acknowledgements

This project was supported by the Natural Science Foundation of China (grant No. 20771003).

References

Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Castillo-Villalón, P., Ramírez, J. & Maugé, F. (2008). J. Catal. 260, 65-74.
Chianelli, R. R., Berhault, G. & Torres, B. (2009). Catal. Today, 147, 275-286.  [ISI] [CrossRef] [ChemPort]
David, D., Silvia, E. & Castillo, B. (2005). J. Phys. Chem. B, 109, 22715-22724.  [PubMed]
Jain, P. U., Munshi, P., Walawalkar, M. G., Rath, S. P., Rajak, K. K. & Lahiri, G. K. (2000). Polyhedron, 19, 801-808.  [ISI] [CSD] [CrossRef] [ChemPort]
Leung, W. H., Lau, K. K., Zhang, Q. F., Wong, W. T. & Tang, B. (2000). Organometallics, 19, 2084-2089.  [CrossRef] [ChemPort]
Liu, X., Zhang, Q. F. & Leung, W. H. (2005). J. Coord. Chem. 58, 1299-1305.  [ISI] [CSD] [CrossRef] [ChemPort]
Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [details]
Wu, F. H., Duan, T., Lu, L., Zhang, Q. F. & Leung, W. H. (2009). J. Organomet. Chem. 694, 3844-3851.  [CSD] [CrossRef] [ChemPort]


Acta Cryst (2013). E69, m341  [ doi:10.1107/S1600536813014141 ]

This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.