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Acta Cryst. (2013). E69, m328
[ doi:10.1107/S1600536813013056 ]

Tetraphenylphosphonium [[mu]3-(4-methylphenyl)tellurolato]tris[tetracarbonyliron(0)]

Y.-L. Li, B. Xie and L.-K. Zou

Abstract: In the anion of the title compound, (C24H20P)[Fe3(C7H7Te)(CO)12], each Fe0 atom is coordinated by four CO ligands and a Te atom, resulting in a trigonal-bipyramidal coordination environment. The Te atom is coordinated by a 4-methylphenyl group and the Fe0 atoms in a distorted tetrahedral geometry. The average Te-Fe bond length is 2.574 (4) Å.

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