Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 6 (June 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m328    [ doi:10.1107/S1600536813013056 ]

Tetra­phenyl­phospho­nium [[mu]3-(4-methyl­phen­yl)tellurolato]tris­[tetra­carbonyl­iron(0)]

Y.-L. Li, B. Xie and L.-K. Zou

Abstract: In the anion of the title compound, (C24H20P)[Fe3(C7H7Te)(CO)12], each Fe0 atom is coordinated by four CO ligands and a Te atom, resulting in a trigonal-bipyramidal coordination environment. The Te atom is coordinated by a 4-methyl­phenyl group and the Fe0 atoms in a distorted tetra­hedral geometry. The average Te-Fe bond length is 2.574 (4) Å.

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