Acta Cryst. (2013). E69, i33 [ doi:10.1107/S1600536813011847 ]
Abstract: In the title salt, [Hg(NCS)(CH4N2S)3]Cl, the Hg2+ ion is coordinated in a severely distorted tetrahedral manner by three thiourea groups and one thiocyanate anion through their S atoms. The S-Hg-S angles vary widely from 87.39 (5) to 128.02 (4)°. Weak intramolecular N-HS hydrogen bonds are observed, which form S(6) ring motifs. In the crystal, the ions are linked by N-HN and weak N-HCl interactions, generating a three-dimensional network.
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