Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 6 (June 2013)


inorganic compounds



Acta Cryst. (2013). E69, i33    [ doi:10.1107/S1600536813011847 ]

(Thiocyanato-[kappa]S)tris(thiourea-[kappa]S)mercury(II) chloride

A. Shihabuddeen Syed, K. Rajarajan and M. NizamMohideen

Abstract: In the title salt, [Hg(NCS)(CH4N2S)3]Cl, the Hg2+ ion is coordinated in a severely distorted tetrahedral manner by three thiourea groups and one thiocyanate anion through their S atoms. The S-Hg-S angles vary widely from 87.39 (5) to 128.02 (4)°. Weak intramolecular N-H...S hydrogen bonds are observed, which form S(6) ring motifs. In the crystal, the ions are linked by N-H...N and weak N-H...Cl interactions, generating a three-dimensional network.


htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file
[ doi:10.1107/S1600536813011847/jj2165sup0.html ]
Supplementary materials


Notes:

To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster