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Acta Cryst. (2013). E69, o833
[ doi:10.1107/S1600536813011604 ]

15-Methoxy-14,15-dihydroandranginine

D.-L. Wang, X.-H. Cai, P. Huang and H.-P. Huang

Abstract: The title polycyclic alkaloid, C22H26N2O3, an indole derivative obtained from Melodinus yunnanensis, comprises three chiral C atoms and crystallizes as a racemate. Its seven-membered heterocyclic ring has a twisted conformation, with the N atom within the plane of the indole moiety and with two adjacent C atoms deviating in opposite directions from its plane by 0.756 (3) (methylene C) and -0.802 (3) Å (methine C). In the crystal, pairs of N-H...O hydrogen bonds connect the molecules into centrosymmetric dimers.


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