Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 6 (June 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m334    [ doi:10.1107/S1600536813013378 ]

(Cyclo­butane-1,1-di­carboxyl­ato-[kappa]2O,O')(1,10-phenanthroline-[kappa]2N,N')platinum(II) dihydrate

P. Starha and Z. Trávnícek

Abstract: The title compound, [Pt(C6H6O4)(C12H8N2)]·2H2O, which crystallizes as two independent formula units, has the metal atom in a square-planar geometry defined by two O atoms of the chelating cyclo­butane-1,1-di­carboxyl­ate dianion and two N atoms of the chelating 1,10-phenanthroline mol­ecule (r.m.s. deviations of the PtO2N2 units = 0.026 and 0.026 Å). Adjacent complex and water mol­ecules are connected through inter­molecular O-H...O hydrogen bonds and C-H...O, C...O [shortest C...O distance = 3.140 (5) Å], [pi]-[pi] [shortest C...C distances = 3.234 (6) and 3.347 (6) Å] and Pt...[pi] [shortest Pt...C distance = 3.358 (4) Å] inter­actions into a three-dimensional network.

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