[Open access]

[Contents scheme]

Acta Cryst. (2013). E69, o959
[ doi:10.1107/S1600536813013846 ]

N,N-Dimethyldehydroabietylammonium chloride ethanol monosolvate

X.-Z. Huang, X.-P. Rao and Y.-J. Cui

Abstract: The title compound {systematic name: 1-[(1R,4aS,10aR)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthren-1-yl]-N,N-dimethylmethanaminium chloride ethanol monosolvate}, C22H36N+·Cl-·C2H6O, was synthesized from dehydroabietylamine by N-methylation with formaldehyde/formic acid and transformation into the hydrochloride. The dehydroabietyl moiety exhibits the usual conformation with the two cyclohexane rings in chair and half-chair conformations and a trans-ring junction. The crystal structure is built up from columns of the dehydroabietyl moieties stacked along the a axis. These columns are held together by the chloride ions via N-H...Cl and C-H...Cl interactions, which establish a two-dimensional network parallel to (010). The ethanol solvent molecules are located between the columns and anchored via O-H...Cl hydrogen bonds.

Copyright © International Union of Crystallography
IUCr Webmaster