Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 6 (June 2013)


organic compounds



rz5061 scheme

Acta Cryst. (2013). E69, o903-o904    [ doi:10.1107/S1600536813012580 ]

4-[(E)-(4-Ethoxybenzylidene)amino]phenol

N. Kaewmanee, S. Chantrapromma, N. Boonnak and H.-K. Fun

Abstract: The molecule of the title compound, C15H15NO2, adopts a trans conformation with respect to the methylidene C=N bond and is twisted with a dihedral angle of 26.31 (5)° between the two substituted benzene rings. The ethoxy group is almost coplanar with the bound benzene ring with a C-O-C-C torsion angle of -179.08 (9)°. In the crystal, molecules are linked by O-H...N hydrogen bonds and weak C-H...O interactions into chains propagating in the [011] and [01-1] directions. C-H...[pi] interactions are also present.


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