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Volume 69 
Part 6 
Pages m335-m336  
June 2013  

Received 11 May 2013
Accepted 12 May 2013
Online 22 May 2013

Key indicators
Single-crystal X-ray study
T = 296 K
Mean [sigma](C-C) = 0.002 Å
R = 0.030
wR = 0.097
Data-to-parameter ratio = 26.8
Details
Open access

(Adipato-[kappa]2O,O')diaqua[bis(pyridin-2-yl-[kappa]N)amine]cobalt(II) trihydrate

aDépartement de Technologie, Faculté de Technologie, Université 20 Août 1955 de Skikda, 21000 Skikda, Algeria,bUnité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Université Constantine I, 25000 Constantine, Algeria,cLaboratoire de Chimie, Ingénierie Moléculaire et Nanostructures (LCIMN), Université Ferhat Abbas, Sétif I, 19000 Sétif, Algeria,dScience and Engineering Faculty, Queensland University of Technology, GPO Box 2434, Brisbane 4001, Australia,eClermont Université, Université Blaise Pascal, Institut de Chimie de Clermont-Ferrand, BP 10448, 63000 Clermont-Ferrand, France, and fCNRS UMR 6296, ICCF, BP 80026, 63171 Aubière, France
Correspondence e-mail: fat_setifi@yahoo.fr, g.smith@qut.edu.au

In the monomeric title complex, [Co(C6H8O4)(C10H9N3)(H2O)2]·3H2O, the distorted octahedral CoN2O4 coordination environment comprises two N-atom donors from the bidentate dipyridyldiamine ligand, two O-atom donors from one of the carboxylate groups of the bidentate chelating adipate ligand and two water molecules. In addition, there are three solvent water molecules which are involved in both intra- and inter-unit O-H...O hydrogen-bonding interactions, which together with an amine-water N-H...O hydrogen bond produce a three-dimensional framework.

Related literature

For the background to metal-dicarboxylate complexes, see: Rao et al. (2004[Rao, C. N. R., Natarajan, S. & Vaidhyanathan, R. (2004). Angew. Chem. Int. Ed. Engl. 43, 1466-1496.]); Setifi et al. (2006[Setifi, F., Bouchama, A., Sala-Pala, J., Salaün, J.-Y. & Triki, S. (2006). Inorg. Chim. Acta, 359, 3269-3274.], 2007[Setifi, F., Benmansour, S., Triki, S., Gómez-García, C. J., Marchivie, M., Salaün, J.-Y. & Maamache, M. (2007). Inorg. Chim. Acta, 360, 3879-3886.]); Wen et al. (2010[Wen, G.-L., Wang, Y.-Y., Zhang, W.-H., Ren, C., Liu, R.-T. & Shi, Q.-Z. (2010). CrystEngComm, 12, 1238-1251.]).

[Scheme 1]

Experimental

Crystal data
  • [Co(C6H8O4)(C10H9N3)(H2O)2]·3H2O

  • Mr = 464.34

  • Triclinic, [P \overline 1]

  • a = 9.9587 (3) Å

  • b = 10.5458 (3) Å

  • c = 11.0885 (3) Å

  • [alpha] = 100.887 (1)°

  • [beta] = 105.891 (1)°

  • [gamma] = 107.889 (1)°

  • V = 1017.38 (5) Å3

  • Z = 2

  • Mo K[alpha] radiation

  • [mu] = 0.90 mm-1

  • T = 296 K

  • 0.26 × 0.21 × 0.18 mm

Data collection
  • Bruker APEXII CCD diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2008[Bruker (2008). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.800, Tmax = 0.855

  • 28998 measured reflections

  • 8197 independent reflections

  • 6984 reflections with I > 2[sigma](I)

  • Rint = 0.024

Refinement
  • R[F2 > 2[sigma](F2)] = 0.030

  • wR(F2) = 0.097

  • S = 0.99

  • 8197 reflections

  • 306 parameters

  • 1 restraint

  • H atoms treated by a mixture of independent and constrained refinement

  • [Delta][rho]max = 0.37 e Å-3

  • [Delta][rho]min = -0.34 e Å-3

Table 1
Selected bond lengths (Å)

Co1-O1 2.0680 (10)
Co1-O2 2.3079 (9)
Co1-O5 2.0877 (12)
Co1-O6 2.1336 (9)
Co1-N1 2.0781 (9)
Co1-N2 2.0596 (10)

Table 2
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
N3-H3...O9i 0.78 (2) 2.05 (2) 2.8228 (17) 172 (2)
O5-H51...O7ii 0.775 (19) 1.923 (19) 2.6933 (15) 172.7 (19)
O5-H52...O3iii 0.80 (2) 1.97 (2) 2.7706 (17) 173 (2)
O6-H61...O2iv 0.83 (2) 2.00 (2) 2.8278 (12) 178 (4)
O6-H62...O8 0.77 (2) 1.94 (2) 2.7056 (16) 170 (2)
O7-H71...O3v 0.74 (3) 2.56 (3) 3.2596 (18) 160 (3)
O7-H72...O1 0.89 (2) 1.86 (2) 2.7543 (16) 175 (2)
O8-H81...O4v 0.88 (3) 1.97 (3) 2.8221 (19) 163 (2)
O8-H82...O4vi 0.79 (3) 2.05 (3) 2.832 (2) 175 (3)
O9-H91...O3vii 0.77 (2) 2.12 (2) 2.8670 (17) 164 (2)
O9-H92...O3v 0.79 (3) 1.99 (3) 2.7452 (17) 160 (3)
Symmetry codes: (i) -x+1, -y+1, -z; (ii) -x+2, -y+1, -z; (iii) -x+3, -y+1, -z+1; (iv) -x+2, -y+1, -z+1; (v) -x+3, -y+2, -z+1; (vi) x-1, y, z; (vii) x-1, y, z-1.

Data collection: APEX2 (Bruker, 2008[Bruker (2008). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2008[Bruker (2008). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: ORTEP-3 for Windows (Farrugia, 2012[Farrugia, L. J. (2012). J. Appl. Cryst. 45, 849-854.]) and PLATON (Spek, 2009[Spek, A. L. (2009). Acta Cryst. D65, 148-155.]); software used to prepare material for publication: PLATON and publCIF (Westrip, 2010[Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.]).


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: SJ5322 ).


Acknowledgements

We are grateful for financial assistance from the DG-RSDT and ANDRU (Diretion Générale de la Recherche Scientifique et du Développement Technologique et l'Agence Nationale pour le Développement de la Recherche Universitaire, Algéria) through the PNR project.

References

Bruker (2008). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Farrugia, L. J. (2012). J. Appl. Cryst. 45, 849-854.  [ISI] [CrossRef] [ChemPort] [details]
Rao, C. N. R., Natarajan, S. & Vaidhyanathan, R. (2004). Angew. Chem. Int. Ed. Engl. 43, 1466-1496.  [ISI] [CrossRef] [PubMed] [ChemPort]
Setifi, F., Benmansour, S., Triki, S., Gómez-García, C. J., Marchivie, M., Salaün, J.-Y. & Maamache, M. (2007). Inorg. Chim. Acta, 360, 3879-3886.  [ISI] [CSD] [CrossRef] [ChemPort]
Setifi, F., Bouchama, A., Sala-Pala, J., Salaün, J.-Y. & Triki, S. (2006). Inorg. Chim. Acta, 359, 3269-3274.  [ISI] [CSD] [CrossRef] [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [details]
Spek, A. L. (2009). Acta Cryst. D65, 148-155.  [ISI] [CrossRef] [ChemPort] [details]
Wen, G.-L., Wang, Y.-Y., Zhang, W.-H., Ren, C., Liu, R.-T. & Shi, Q.-Z. (2010). CrystEngComm, 12, 1238-1251.  [ISI] [CSD] [CrossRef] [ChemPort]
Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.  [ISI] [CrossRef] [ChemPort] [details]


Acta Cryst (2013). E69, m335-m336   [ doi:10.1107/S1600536813012981 ]

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