Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 6 (June 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m335-m336    [ doi:10.1107/S1600536813012981 ]

(Adipato-[kappa]2O,O')di­aqua­[bis­(pyridin-2-yl-[kappa]N)amine]­cobalt(II) trihydrate

Z. Setifi, F. Setifi, G. Smith, M. El-Ghozzi, D.-A. Rouag, D. Avignant and H. Merazig

Abstract: In the monomeric title complex, [Co(C6H8O4)(C10H9N3)(H2O)2]·3H2O, the distorted octa­hedral CoN2O4 coordination environment comprises two N-atom donors from the bidentate di­pyridyldi­amine ligand, two O-atom donors from one of the carboxyl­ate groups of the bidentate chelating adipate ligand and two water mol­ecules. In addition, there are three solvent water mol­ecules which are involved in both intra- and inter-unit O-H...O hydrogen-bonding inter­actions, which together with an amine-water N-H...O hydrogen bond produce a three-dimensional framework.

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