Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 6 (June 2013)


metal-organic compounds



sj5322 scheme

Acta Cryst. (2013). E69, m335-m336    [ doi:10.1107/S1600536813012981 ]

(Adipato-[kappa]2O,O')diaqua[bis(pyridin-2-yl-[kappa]N)amine]cobalt(II) trihydrate

Z. Setifi, F. Setifi, G. Smith, M. El-Ghozzi, D.-A. Rouag, D. Avignant and H. Merazig

Abstract: In the monomeric title complex, [Co(C6H8O4)(C10H9N3)(H2O)2]·3H2O, the distorted octahedral CoN2O4 coordination environment comprises two N-atom donors from the bidentate dipyridyldiamine ligand, two O-atom donors from one of the carboxylate groups of the bidentate chelating adipate ligand and two water molecules. In addition, there are three solvent water molecules which are involved in both intra- and inter-unit O-H...O hydrogen-bonding interactions, which together with an amine-water N-H...O hydrogen bond produce a three-dimensional framework.


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