Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 6 (June 2013)


metal-organic compounds



su2595 scheme

Acta Cryst. (2013). E69, m313    [ doi:10.1107/S1600536813012622 ]

Aquatrimethyl[2-(4-methylpyrimidin-2-ylsulfanyl)acetato-[kappa]O]tin(IV)

Z. Gao, J. Zhang, X. Hao, D. Wang and T. Zhang

Abstract: In the title compound, [Sn(CH3)3(C7H7N2O2S)(H2O)], the SnIV atom has a distorted trigonal-bipyramidal coordination geometry, with one carboxylate O atom of the 2-(4-methylpyrimidine-2-sulfanyl)acetate ligand and the O atom of a water molecule in axial positions, and three methyl groups in equatorial positions. In the crystal, molecules are linked via O-H...O and O-H...N hydrogen bonds, forming double-stranded chains propagating along [010].


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