Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 6 (June 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m322    [ doi:10.1107/S1600536813012816 ]

[Hexane-2,5-dione bis­(thio­semi­carba­zon­ato)]nickel(II)

M. S. Shalamzari, A. V. Gurbanov, S. Heidic, R. Kia and S. Behrouzi

Abstract: In the title compound, [Ni(C8H14N6S2)], the NiII ion is coordinated by N2S2 donor atoms of the tetradentate thio­semicarbazone ligand, and has a slightly distorted square-planar geometry. In the crystal, inversion-related mol­ecules are linked via pairs of N-H...N and N-H...S hydrogen bonds, forming R22(8) ring motifs. Mol­ecules are further linked by slightly weaker N-H...N, N-H...S and C-H...S hydrogen bonds, forming two-dimensional networks which lie parallel to the bc plane.

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