Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 6 (June 2013)


metal-organic compounds



wm2742 scheme

Acta Cryst. (2013). E69, m323-m324    [ doi:10.1107/S1600536813013032 ]

Bis{(Z)-[(E)-2-(pyridin-2-ylmethylidene)hydrazin-1-ylidene][(pyridin-2-yl)methylsulfanyl]methanethiolato}nickel(II)

T.-J. Khoo, M. K. bin Break, M. I. M. Tahir, K. A. Krouse, A. R. Cowley and D. J. Watkin

Abstract: The title compound, [Ni(C13H11N4S2)2], was obtained by the reaction of S-2-picolyldithiocarbazate and pyridine-2-carbaldehyde with nickel(II) acetate. The NiII atom is located on a twofold rotation axis and is bonded to four N atoms at distances of 2.037 (8) and 2.109 (9) Å, and to two S atoms at a distance of 2.406 (3) Å, leading to a distorted octahedral coordination. The angle between the mean planes of the coordinating moieties of the two symmetry-related tridentate ligands is 83.3 (2)°. In the crystal, complex molecules are linked by weak C-H...S hydrogen bonds, [pi]-[pi] interactions between the pyridine rings [centroid-centroid distance = 3.775 (9) Å] and C-H...[pi] interactions. The hydrogen-bonding interactions lead to the formation of layers parallel to (010); [pi]-[pi] interactions link these layers into a three-dimensional network.


htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file
[ doi:10.1107/S1600536813013032/wm2742sup0.html ]
Supplementary materials


moldisplay filedownload file

MDL mol file (6.1 kbytes)
[ doi:10.1107/S1600536813013032/wm2742Isup3.mol ]
Supplementary material


Notes:

To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster