[Open access]

[Contents scheme]

Acta Cryst. (2013). E69, m342
[ doi:10.1107/S160053681301413X ]

catena-Poly[[(triphenylphosphane-[kappa]P)silver(I)]-[mu]-4,4'-bipyridine-[kappa]2N:N'-[(triphenylphosphane-[kappa]P)silver(I)]-di-[mu]-chlorido]

X.-M. Song, F. Hu, H.-T. Shi, Q. Chen and Q.-F. Zhang

Abstract: In the title coordination polymer, [Ag2Cl2(C10H8N2)(C18H15P)2]n, the AgI cation is coordinated by a 4,4'-bipyridine N atom, a triphenylphosphane P atom and two Cl- anions in a distorted tetrahedral geometry. The 4,4-bipyridine and Cl- anions bridge the AgI cations, forming polymeric chains running along [21-1]. In the crystal, weak C-H...Cl interactions link the polymeric chains into a three-dimensiona supramolecular architecture.


Copyright © International Union of Crystallography
IUCr Webmaster