[Journal logo]

Volume 69 
Part 6 
Page m342  
June 2013  

Received 8 May 2013
Accepted 21 May 2013
Online 25 May 2013

Key indicators
Single-crystal X-ray study
T = 296 K
Mean [sigma](C-C) = 0.005 Å
R = 0.039
wR = 0.092
Data-to-parameter ratio = 19.7
Details
Open access

catena-Poly[[(triphenylphosphane-[kappa]P)silver(I)]-[mu]-4,4'-bipyridine-[kappa]2N:N'-[(triphenylphosphane-[kappa]P)silver(I)]-di-[mu]-chlorido]

aDepartment of Applied Chemistry, School of Petrochemical Engineering, Changzhou University, Jiangsu 213164, People's Republic of China, and bInstitute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma'anshan, Anhui 243002, People's Republic of China
Correspondence e-mail: zhangqf@ahut.edu.cn

In the title coordination polymer, [Ag2Cl2(C10H8N2)(C18H15P)2]n, the AgI cation is coordinated by a 4,4'-bipyridine N atom, a triphenylphosphane P atom and two Cl- anions in a distorted tetrahedral geometry. The 4,4-bipyridine and Cl- anions bridge the AgI cations, forming polymeric chains running along [21-1]. In the crystal, weak C-H...Cl interactions link the polymeric chains into a three-dimensiona supramolecular architecture.

Related literature

For background to silver coordination polymers, see: Hung-Low & Klausmeyer (2008[Hung-Low, F. & Klausmeyer, K. K. (2008). Inorg. Chim. Acta, 361, 1298-1310.]); Mishra et al. (2007[Mishra, L., Prajapati, R., Kimura, K. & Kobayashi, S. (2007). Inorg. Chem. Commun. 10, 1040-1044.]); Pyykkö (2004[Pyykkö, P. (2004). Angew. Chem., Int. Ed. Engl. 43, 4412-4456.]); Yam & Lo (1999[Yam, V. W. W. & Lo, K. K. W. (1999). Chem. Soc. Rev. 28, 323-334.]); Zaworotko (1994[Zaworotko, M. J. (1994). Chem. Soc. Rev. 23, 283-288.]). For related structures, see: Lu et al. (1997[Lu, J., Crisci, G., Niu, T. & Jacobson, A. J. (1997). Inorg. Chem. 36, 796-801.]); Sampanthar & Vittal (2000[Sampanthar, J. T. & Vittal, J. J. (2000). Cryst. Eng. 3, 117-133.]); Sun et al. (2009[Sun, D., Luo, G.-G., Zhang, N., Huang, R.-B. & Zheng, L.-S. (2009). Acta Cryst. C65, m440-m442.]).

[Scheme 1]

Experimental

Crystal data
  • [Ag2Cl2(C10H8N2)(C18H15P)2]

  • Mr = 967.36

  • Triclinic, [P \overline 1]

  • a = 9.1042 (16) Å

  • b = 13.887 (2) Å

  • c = 17.826 (3) Å

  • [alpha] = 70.753 (3)°

  • [beta] = 79.332 (4)°

  • [gamma] = 75.190 (3)°

  • V = 2044.5 (6) Å3

  • Z = 2

  • Mo K[alpha] radiation

  • [mu] = 1.20 mm-1

  • T = 296 K

  • 0.23 × 0.17 × 0.14 mm

Data collection
  • Bruker SMART APEXII CCD area-detector diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2001[Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.770, Tmax = 0.850

  • 14039 measured reflections

  • 9594 independent reflections

  • 6338 reflections with I > 2[sigma](I)

  • Rint = 0.018

Refinement
  • R[F2 > 2[sigma](F2)] = 0.039

  • wR(F2) = 0.092

  • S = 1.01

  • 9594 reflections

  • 487 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.59 e Å-3

  • [Delta][rho]min = -0.44 e Å-3

Table 1
Selected bond lengths (Å)

Ag1-P1 2.4069 (9)
Ag1-N1 2.430 (3)
Ag1-Cl1 2.5709 (10)
Ag1-Cl1i 2.6639 (10)
Ag2-P2 2.4162 (9)
Ag2-N2 2.386 (3)
Ag2-Cl2 2.6111 (9)
Ag2-Cl2ii 2.6809 (10)
Symmetry codes: (i) -x+1, -y+2, -z+1; (ii) -x-1, -y+1, -z+2.

Table 2
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
C9-H9...Cl2iii 0.93 2.82 3.669 (4) 153
Symmetry code: (iii) x+1, y, z.

Data collection: APEX2 (Bruker, 2007[Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2007[Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: XU5704 ).


Acknowledgements

This project was supported by the Natural Science Foundation of China (90922008).

References

Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2007). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Hung-Low, F. & Klausmeyer, K. K. (2008). Inorg. Chim. Acta, 361, 1298-1310.  [ChemPort]
Lu, J., Crisci, G., Niu, T. & Jacobson, A. J. (1997). Inorg. Chem. 36, 796-801.
Mishra, L., Prajapati, R., Kimura, K. & Kobayashi, S. (2007). Inorg. Chem. Commun. 10, 1040-1044.  [ISI] [CrossRef] [ChemPort]
Pyykkö, P. (2004). Angew. Chem., Int. Ed. Engl. 43, 4412-4456.
Sampanthar, J. T. & Vittal, J. J. (2000). Cryst. Eng. 3, 117-133.  [CSD] [CrossRef] [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [details]
Sun, D., Luo, G.-G., Zhang, N., Huang, R.-B. & Zheng, L.-S. (2009). Acta Cryst. C65, m440-m442.  [CSD] [CrossRef] [ChemPort] [details]
Yam, V. W. W. & Lo, K. K. W. (1999). Chem. Soc. Rev. 28, 323-334.  [ISI] [CrossRef] [ChemPort]
Zaworotko, M. J. (1994). Chem. Soc. Rev. 23, 283-288.  [CrossRef] [ChemPort] [ISI]


Acta Cryst (2013). E69, m342  [ doi:10.1107/S160053681301413X ]

This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.