Received 8 May 2013
aDepartment of Applied Chemistry, School of Petrochemical Engineering, Changzhou University, Jiangsu 213164, People's Republic of China, and bInstitute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma'anshan, Anhui 243002, People's Republic of China
Correspondence e-mail: email@example.com
In the title coordination polymer, [Ag2Cl2(C10H8N2)(C18H15P)2]n, the AgI cation is coordinated by a 4,4'-bipyridine N atom, a triphenylphosphane P atom and two Cl- anions in a distorted tetrahedral geometry. The 4,4-bipyridine and Cl- anions bridge the AgI cations, forming polymeric chains running along [21-1]. In the crystal, weak C-HCl interactions link the polymeric chains into a three-dimensiona supramolecular architecture.
For background to silver coordination polymers, see: Hung-Low & Klausmeyer (2008); Mishra et al. (2007); Pyykkö (2004); Yam & Lo (1999); Zaworotko (1994). For related structures, see: Lu et al. (1997); Sampanthar & Vittal (2000); Sun et al. (2009).
Data collection: APEX2 (Bruker, 2007); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: XU5704 ).
This project was supported by the Natural Science Foundation of China (90922008).
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