Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 6 (June 2013)

metal-organic compounds

Acta Cryst. (2013). E69, m319    [ doi:10.1107/S1600536813012609 ]

catena-Poly[[[bis­(methanol-[kappa]O)bis­(seleno­cyanato-[kappa]N)manganese(II)]-[mu]-1,2-bis­(pyridin-4-yl)eth­ene-[kappa]2N:N'] 1,2-bis­(pyridin-4-yl)eth­ene mono­solvate]

S. Wöhlert, I. Jess and C. Näther

Abstract: In the crystal structure of the title compound, {[Mn(NCSe)2(C12H10N2)(CH3OH)2]·C12H10N2}n, the MnII cation is coordin­ated by two terminal N-bonded seleno­cyanate anions, two methanol mol­ecules and two 1,2-bis­(pyridin-4-yl)eth­ene (bpe) ligands within a slightly distorted octahedral geometry. The MnII cations are linked into chains along the c-axis direction by the bpe ligands, which are further connected by inter­molecular O-H...N hydrogen bonding between the methanol H atoms and additional bpe mol­ecules that are not coordinated to the metal atoms. The MnII cation and both crystallographically independent bpe ligands are located on centers of inversion, whereas the seleno­cyanate and methanol ligands occupy general positions.

htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file
[ doi:10.1107/S1600536813012609/zl2549sup0.html ]
Supplementary materials


To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster