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Volume 69 
Part 7 
Pages m364-m365  
July 2013  

Received 14 May 2013
Accepted 27 May 2013
Online 8 June 2013

Key indicators
Single-crystal X-ray study
T = 100 K
Mean [sigma](C-C) = 0.004 Å
R = 0.026
wR = 0.063
Data-to-parameter ratio = 31.6
Details
Open access

Dichloridobis(pyridine-2-selenolato-[kappa]2N,Se)tin(IV)

aBaku State University, Z. Khalilov Street 23, Baku AZ-1148, Azerbaijan,bR. E. Alekseev Nizhny Novgorod State Technical University, 24 Minin Street, Nizhny Novgorod 603950, Russian Federation, and cX-Ray Structural Centre, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Street, B-334 Moscow 119991, Russian Federation
Correspondence e-mail: isheydi02@gmail.com

The title compound, [SnCl2(C5H4NSe)2], is the product of a reaction of 2,2'-dipyridyl diselenide with tin tetrachloride. The molecule is located about a twofold rotation axis. The coordination environment of the SnIV atom is a distorted octahedron, with two bidentate 2-pyridineselenolate ligands inclined to each other at an angle of 83.96 (7)°. The two Sn-Cl and two Sn-N bonds are in cis configurations, while the two Sn-Se bonds of 2.5917 (3) Å are in a trans configuration, with an Se-Sn-Se angle of 157.988 (15)°. In the crystal, [pi]-[pi] interactions between the pyridine rings [centroid-to-centroid distance of 3.758 (3) Å] and weak intermolecular C-H...Cl hydrogen bonds link the molecules into chains along the c axis.

Related literature

For metal complexes with 2,2'-dipyridyl dichalcogenides, see: Kadooka et al. (1976a[Kadooka, M. M., Warner, L. G. & Seff, K. (1976a). J. Am. Chem. Soc. 98, 7569-7578.],b[Kadooka, M. M., Warner, L. G. & Seff, K. (1976b). Inorg. Chem. 15, 812-816.]); Cheng et al. (1996[Cheng, Y., Emge, T. J. & Brennan, J. G. (1996). Inorg. Chem. 35, 342-346.]); Kienitz et al. (1996[Kienitz, C. O., Thöne, C. & Jones, P. G. (1996). Inorg. Chem. 35, 3990-3997.]); Bell et al. (2000[Bell, N. A., Gelbrich, T., Hursthouse, M. B., Mark, E., Light, M. E. & Wilson, A. (2000). Polyhedron, 19, 2539-2546.]); Kita et al. (2001[Kita, M., Tamai, H., Ueta, F., Fuyuhiro, A., Yamanari, K., Nakajima, K., Kojima, M., Murata, K. & Yamashita, S. (2001). Inorg. Chim. Acta, 314, 139-146.]); Kedarnath et al. (2009[Kedarnath, G., Jain, V. K., Wadawale, A. & Dey, G. K. (2009). Dalton Trans. 39, 8378-8385.]). For syntheses and structures of related tin(IV) compounds, see: Masaki & Matsunami (1976[Masaki, M. & Matsunami, S. (1976). Bull. Chem. Soc. Jpn, 49, 3274-3279.]); Masaki et al. (1978[Masaki, M., Matsunami, S. & Ueda, H. (1978). Bull. Chem. Soc. Jpn, 51, 3298-3301.]); Labisbal et al. (1993[Labisbal, E., Romero, J., Duran, M. L., Garcia-Vazquez, J. A., Sousa, A., Russo, U., Pritchard, R. & Renson, M. (1993). J. Chem. Soc. Dalton Trans. pp. 755-758.]); Chopra et al. (1996[Chopra, N., Damude, L. C., Dean, P. A. W. & Vittal, J. J. (1996). Can. J. Chem. 74, 2095-2105.]); Ismaylova et al. (2012[Ismaylova, S. R., Matsulevich, Z. V., Borisova, G. N., Borisov, A. V. & Khrustalev, V. N. (2012). Acta Cryst. E68, m875-m876.]).

[Scheme 1]

Experimental

Crystal data
  • [SnCl2(C5H4NSe)2]

  • Mr = 503.69

  • Monoclinic, C 2/c

  • a = 6.5174 (4) Å

  • b = 13.1221 (8) Å

  • c = 16.3066 (9) Å

  • [beta] = 100.194 (1)°

  • V = 1372.56 (14) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 7.53 mm-1

  • T = 100 K

  • 0.18 × 0.15 × 0.15 mm

Data collection
  • Bruker APEXII CCD diffractometer

  • Absorption correction: multi-scan (SADABS; Sheldrick, 2003[Sheldrick, G. M. (2003). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.344, Tmax = 0.398

  • 9918 measured reflections

  • 2464 independent reflections

  • 2149 reflections with I > 2[sigma](I)

  • Rint = 0.031

Refinement
  • R[F2 > 2[sigma](F2)] = 0.026

  • wR(F2) = 0.063

  • S = 1.00

  • 2464 reflections

  • 78 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.79 e Å-3

  • [Delta][rho]min = -0.87 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
C4-H4...Cl1i 0.95 2.82 3.675 (3) 151
Symmetry code: (i) -x+1, -y+1, -z.

Data collection: APEX2 (Bruker, 2005[Bruker (2005). APEX2. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2001[Bruker (2001). SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: CV5413 ).


Acknowledgements

The authors thank Professor Abel M. Maharramov for fruitful discussions and help in this work.

References

Bell, N. A., Gelbrich, T., Hursthouse, M. B., Mark, E., Light, M. E. & Wilson, A. (2000). Polyhedron, 19, 2539-2546.  [Web of Science] [CSD] [CrossRef] [ChemPort]
Bruker (2001). SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2005). APEX2. Bruker AXS Inc., Madison, Wisconsin, USA.
Cheng, Y., Emge, T. J. & Brennan, J. G. (1996). Inorg. Chem. 35, 342-346.  [CrossRef] [PubMed] [ChemPort] [Web of Science]
Chopra, N., Damude, L. C., Dean, P. A. W. & Vittal, J. J. (1996). Can. J. Chem. 74, 2095-2105.  [CrossRef] [ChemPort] [Web of Science]
Ismaylova, S. R., Matsulevich, Z. V., Borisova, G. N., Borisov, A. V. & Khrustalev, V. N. (2012). Acta Cryst. E68, m875-m876.  [CSD] [CrossRef] [ChemPort] [IUCr Journals]
Kadooka, M. M., Warner, L. G. & Seff, K. (1976a). J. Am. Chem. Soc. 98, 7569-7578.  [CrossRef] [ChemPort] [PubMed] [Web of Science]
Kadooka, M. M., Warner, L. G. & Seff, K. (1976b). Inorg. Chem. 15, 812-816.  [CrossRef] [ChemPort] [Web of Science]
Kedarnath, G., Jain, V. K., Wadawale, A. & Dey, G. K. (2009). Dalton Trans. 39, 8378-8385.  [CSD] [CrossRef] [PubMed]
Kienitz, C. O., Thöne, C. & Jones, P. G. (1996). Inorg. Chem. 35, 3990-3997.  [CrossRef] [PubMed] [ChemPort] [Web of Science]
Kita, M., Tamai, H., Ueta, F., Fuyuhiro, A., Yamanari, K., Nakajima, K., Kojima, M., Murata, K. & Yamashita, S. (2001). Inorg. Chim. Acta, 314, 139-146.  [Web of Science] [CSD] [CrossRef] [ChemPort]
Labisbal, E., Romero, J., Duran, M. L., Garcia-Vazquez, J. A., Sousa, A., Russo, U., Pritchard, R. & Renson, M. (1993). J. Chem. Soc. Dalton Trans. pp. 755-758.  [CrossRef]
Masaki, M. & Matsunami, S. (1976). Bull. Chem. Soc. Jpn, 49, 3274-3279.  [CrossRef] [ChemPort] [Web of Science]
Masaki, M., Matsunami, S. & Ueda, H. (1978). Bull. Chem. Soc. Jpn, 51, 3298-3301.  [CrossRef] [ChemPort] [Web of Science]
Sheldrick, G. M. (2003). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [ChemPort] [IUCr Journals]


Acta Cryst (2013). E69, m364-m365   [ doi:10.1107/S1600536813014657 ]

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