Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 7 (July 2013)

organic compounds

Acta Cryst. (2013). E69, o1160-o1161    [ doi:10.1107/S1600536813017091 ]

N'-[(E)-4-Benz­yloxy-2-hy­droxy­benzyl­idene]-4-nitro­benzohydrazide di­methyl­formamide monosolvate

B. Joseph, M. Sithambaresan and M. R. P. Kurup

Abstract: The title compound, C21H17N3O5·C3H7NO, exists in an E conformation with respect to the azomethine double bond of the hydrazide mol­ecule. This mol­ecule contains an intra­molecular O-H...N hydrogen bond, while an inter­molecular N-H...O hydrogen bond links the hydrazide to the formamide mol­ecule of solvation. Nonclassical C-H...O inter­molecular hydrogen bonds build up a supra­molecular architecture, together with two C-H...[pi] inter­actions and a weak [pi]-[pi] inter­action, with a centroid-centroid distance of 3.650 (13) Å.

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