Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 7 (July 2013)


metal-organic compounds



hy2628 scheme

Acta Cryst. (2013). E69, m416    [ doi:10.1107/S1600536813017121 ]

catena-Poly[(diaquacadmium)-[mu]-iminodiacetato-[kappa]4O,N,O':O'']

G.-H. Pan, J.-N. Tang, Z.-J. Huang, Y.-F. Liao and B.-F. Mo

Abstract: In the title compound, [Cd(C4H5NO4)(H2O)2]n, the CdII atom exhibits a distorted octahedral coordination geometry, defined by one N atom and three O atoms from two iminodiacetate (IDA) ligands and two water molecules. The tridentate IDA ligand additionally bridges via one of its carboxylate O atoms to another CdII atom, thus forming a zigzag chain along [001]. A three-dimensional network is completed by intermolecular O-H...O and N-H...O hydrogen bonds.


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