Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 7 (July 2013)


metal-organic compounds



lh5618 scheme

Acta Cryst. (2013). E69, m368-m369    [ doi:10.1107/S1600536813014992 ]

N,N,N,N',N',N'-Hexakis(2-hydroxyethyl)butane-1,4-diaminium bis(2-sulfanylidene-1,3-dithiole-4,5-dithiolato-[kappa]2S4,S5)zincate

X. Zhang, B. Xie, L. Zou, J. Wang and X. Lin

Abstract: In the asymmetric unit of the title compound, (C16H38N2O6)[Zn(C3S5)2], two independent cations lie across inversion centers. In one of the cations, the three symmetry-unique O-H groups are disordered over two sets of sites with refined occupancy ratios of 0.701 (9):0.299 (9), 0.671 (8):0.329 (8) and 0.566 (7):0.434 (7). In the anion, the ZnII ion is coordinated in a distorted tetrahedral environment by four S atoms of two chelating 1,3-dithiole-2-thione-4,5-dithiolato ligands. The dihedral angle between the mean planes [maximun deviations = 0.022 (3) and 0.0656 (6) Å] of the two ligands is 87.76 (3)°. An intamolecular O-H...O hydrogen bond occurs in the disordered cation. In the crystal, O-H...O and O-H...S hydrogen bonds link the components into a two-dimensional network parallel to (0-11).


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