Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 7 (July 2013)


metal-organic compounds



rn2115 scheme

Acta Cryst. (2013). E69, m374-m375    [ doi:10.1107/S160053681301516X ]

cis-Bromido(methylamine)bis(propane-1,3-diamine)cobalt(III) dibromide

P. S. Kannan, A. S. Ganeshraja, K. Anbalagan, E. Govindan and A. SubbiahPandi

Abstract: In the title compound, [CoBr(CH5N)(C3H10N2)2]Br2, the cobaltIII ion has a distorted octahedral coordination environment and is surrounded by four N atoms in the equatorial plane, with an additional N atom and the Br atom occupying the axial positions. In the crystal, the complex cation and the two counter anions are linked via N-H...Br and C-H...Br hydrogen bonds, forming a three-dimensional network.


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