Acta Crystallographica Section E

Structure Reports Online

Volume 69, Part 7 (July 2013)


metal-organic compounds



rz5068 scheme

Acta Cryst. (2013). E69, m383    [ doi:10.1107/S1600536813015882 ]

Poly[bis{[mu]-N'-[(pyridin-4-yl)methylidene]benzohydrazidato}copper(II)]

Q. Wu, D.-C. Chen, C.-Y. Wu, C.-X. Yan and J.-Z. Liao

Abstract: In the title complex, [Cu(C13H10N3O)2]n, the copper(II) cation is located on a crystallographic inversion centre and adopts an elongated octahedral coordination geometry with the equatorial plane provided by trans-arranged bis-N,O-chelating acylhydrazine groups from two ligands and the apices by the N atoms of two pyridine rings belonging to symmetry-related ligands. The ligand adopts a Z conformation about the C=N double bond. The dihedral angle between the pyridine and phenyl rings is 2.99 (13)°. An intraligand C-H...N hydrogen bond is observed. In the crystal, each ligand bridges two adjacent metal ions, forming a (4,4) grid layered structure. [pi]-[pi] stacking interactions [centroid-centroid distances in the range 3.569 (4)-3.584 (9) Å] involving rings of adjacent layers result in the formation of a three-dimensional supramolecular network.


htmldisplay filedownload file

Hyper-Text Markup Language (HTML) file
[ doi:10.1107/S1600536813015882/rz5068sup0.html ]
Supplementary materials


Notes:

To open or display or play some files, you may need to set your browser up to use the appropriate software. See the full list of file types for an explanation of the different file types and their related mime types and, where available links to sites from where the appropriate software may be obtained.

The download button will force most browsers to prompt for a file name to store the data on your hard disk.

Where possible, images are represented by thumbnails.

 bibliographic record in  format

  Find reference:   Volume   Page   
  Search:     From   to      Advanced search

Copyright © International Union of Crystallography
IUCr Webmaster