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Acta Cryst. (2013). E69, m370  [ doi:10.1107/S1600536813014979 ]

Potassium N-bromo-4-chloro-2-methylbenzenesulfonamidate monohydrate

H. S. Spandana, S. Foro and B. T. Gowda

Abstract: In the title compound, K+·C7H6BrClNO2S-·H2O, the K+ cation is heptacoordinated by two water O atoms, four sulfonyl O atoms of four different N-bromo-4-chloro-2-methylbenzenesulfonamidate anions, and one Br atom of one of the anions. The S-N distance of 1.584 (3) Å is consistent with an S=N double bond. In the crystal, the anions are linked into layers by O-H...Br and O-H...N hydrogen bonds.


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