Acta Cryst. (2013). E69, o1149 [ doi:10.1107/S1600536813016371 ]
Abstract: The naphthol-containing molecule of the title compound, C10H6Br2O·CH3OH, crystallized as a methanol monosolvate and is planar to within 0.069 (1) Å for all non-H atoms. In the crystal, molecules are linked by two pairs of O-HO hydrogen bonds, involving the methanol molecule, forming dimer-like arrangements. The crystal structure is further stabilized by - stacking [centroid-centroid distance = 3.676 (2) Å] and BrBr interactions [3.480 (4) and 3.786 (1) Å], forming a three-dimensional structure.
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